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Showing posts with label perfumery. Show all posts
Showing posts with label perfumery. Show all posts

Saturday, April 27

iPigeon.institute Local Botanical Item Spotlights - Mitica brand honeycomb, from Gelson's.

Update, and quick note: yipes! This product could potentially cause severe eye irritation! Be very wary about using the product described in this blog article, as far as cosmetic use goes. 


 One of my more recent fragrance fascinations was with the raw material, the honeycomb. I'd once had a great sample of Beeswax Absolute, which I highly enjoyed, and, which I'd mixed in to some fragrance compositions, with some slight attainment about them. I found the material very overpoweringly dominant, in what I felt, at the time, were small portions (I was just beginning to investigate and experiment with perfumery materials, having come from a background in making fragrance compositions with essential oils and absolutes that are more commonly found in local retail stores. 

In any case, I was fascinated by the physiological, or psychoactive (bioactive, perhaps, at least), effects of Beeswax Absolute, and, once I had run out of my sample product, I'd sometimes obsess over the ingredient, and I'd spend a lot of time, here and there, trying to find out new things to know about the product, itself, and I also developed a fascination with producing the absolute, myself, as well. 

Recently, I came across a great retail product beeswax honeycomb, by Mitica brand, which I found at Gelson's grocery store. I made sure to pick one up, since I had lots of money on my Food Stamps account, still. The item comes in its own frame and plastic box (which, for aroma chemical extraction, might not be the best material, but this is just my first try at producing my own agricultural fragrance ingredient from this material).

A top view of Mitica brand's honeycomb box, which includes a frame that the beeswax and honey, contained within the honeycomb, is built upon.

A diagonal view of Mitica's honeycomb box and frame. I felt that the product was ideal, over other choices in retail honeycomb availability, particularly on account of that a box and frame are included with the product.
I had not much knowledge base to work from, as far as discovering literature in regards to the chemical and molecular composition and form of honeycomb and beeswax material, so I had to do some looking up, of things. I had some notion that I could try to produce an alternative product to an absolute, using regular cooking vinegar. I tried it out, by soaking the honeycomb frame, in the box, and I felt that it could take weeks, or months, or more, perhaps, for a full extraction, as limited as with vinegar, solely, as the extraction fluid, although evaporation would be fairly reliable, I figured, and there could be useful compounds produced, with acetic acid thrown in to the equation, given that I be patient. 

At this point, it's been a few weeks, or so, and I noticed some slight changes - almost of that the beeswax seemed almost alive, in and of itself, even under vinegar, since I felt that some of the beeswax seemed to have creeped along, further out, on to the frame's top edges, where I don't remember seeing beeswax establishments, previously. The vinegar solution, itself, slowly became yellowish, but there wasn't a whole lot of action, in this instance of experimentation. 

Upon investigating the solvency considerations of the material, it was learned that the extraction would be best done with a polar solvent. I don't have any of the standard solvents, on hand, but, at one point, I became reminded that I have dimethyl octenone on hand, of which, I'd had previously employed a similar (somewhat) product, in doing an extraction and production method, as an experiment, with 3-octanone, as part of the extraction. Dimethyl octenone has a fairly relative olfactory scent profile to 3-octanone, and I figured that it is a polar solvent, in and of itself, perhaps as a scarce fraction of some other, more gross product of some other agricultural crop, in being separated, for qualitative purposes.

With a 15 mL bottle of dimethyl octenone, I was capable of pouring around a third, or less,  of the bottle out, in to the vinegar solution, and still cover the entire top surface area. Immediately, I noticed that the two layers didn't immediately mix; it was like oil and water, so I felt that my decision to employ dimethyl octenone was justified. This was yesterday. The liquid in the box became very vaporous, so I felt that perhaps a timeline of an extraction, in this experiment phase, would work along a much quicker timeline. If you'd notice, in the first photo, some of the honeycomb cells are destroyed, over on the top left. There are also some "breathing holes" that had developed, as a result of introducing the dimethyl octenone to the solvent solution (I shook the box, so the liquids became a more thorough solution). I figured, dimethyl octenone, pungent and musky solvent-smelling that it is, it'll eventually evaporate off; I should seek to establish more generalized visible similarities between what I produce, regardless of what it is, specifically, and if the viscosity, or consistency, in terms of the product's thickness, or solidity, becomes a familiar and standard sort of outcome, it would be easier to sit and wait for this type of portion of patience being necessary, being that dimethyl octenone might only dissipate over several weeks, or so, perhaps. 

Part of the challenge would be discovering what becomes of the wax, itself. I would typically take a "hands-off" approach to playing with my extraction experiments, and just stick to observation, and just the slightest of mixing, or disturbance of the solution, but, in this case, I touched the corner of the beeswax, and it melted like cake frosting, so I knew, then, that the extraction would be successful, from here. Only time will tell, as to what the outcome of this experiment will produce.

Update:

This honeycomb / beeswax project continues to reveal delicate mysteries about its form, within the acidic, polar solvent liquid At this stage, 4 days later, following the original post, the Mitica honeycomb's plastic box proves to have taken on acid damage, bearing leaks, and penetration, through the outer layers of plastic, whereas the now emulsified lipophilic liquid, which has incorporated the beeswax, as liquid beads, as an outer phase of emulsifier, wherein the solvent layer acts as the inner phase, with the dimethyl octenone / acetic acid, perhaps mixed with the plastic, somehow acting as a surfactant, to make the emulsification fairly molecularly small. Have a look! 



This (not so delicate) bulge is pretty resilient, in fact - almost like a rubbery latex, in texture, but definitely bendable and flexible, with the plastic walls having disintegrated, due to the particular nature of the acidic polar solvency of the solution. I'd suppose it would be a perfumer's hand at pulling off this trick; some of it is just gestural artistry, since I didn't know that this would happen - although if you did the same extraction, it very well could happen for you, also. 



Monday, April 25

Product Review: Liberty Natural - Licorice “anise” Air Freshener.

 Recently, I’ve been having a significant hankering for the scent of licorice, and for designing fragrances around a licorice fragrance. That being the case, and being that licorice, in and of itself, is not all that much thought, per se, in perfumery - I came up against some challenges, during the course of my inquiries in to what “stuff” available there could possibly be, on the internet, as far as licorice extracts, etc., of various sorts, for example. I was searching for a licorice absolute, which apparently had been made available, at some point, in the past, at a very small number of suppliers, I’d discovered, after fairly rigorous extents made, of “search,” as it were. At this point, however, I did not discover any supplier for a licorice absolute. 

After discovering Liberty Naturals’ Licorice “anise” Air Freshener, I’d put a small amount of thought into it, and I figured, “hey; they do fragrance extract products fairly well, I’d suppose that this product is fairly well enough, if they say it is an air freshener.” On one hand, that was a fairly well enough thing to suppose, as it turns out, since I purchased the bottle, and it says that it contains 100% essential oil. In some sense, on the matter, getting one or another fragrance extraction, per specimen or per species of plant, will give the creator of a fragrance ingredient, isolate, or extraction product - various options, on one hand, various outcomes, on the other, with variable desirability, with cases in which a particular “this or that” sort of solution that works for one type of plant, winds up not being desirable or ideal, for a different type of plant. In this instance, perhaps a licorice absolute isn’t quite desirable, in industry-informed “types,” such that there could be, upon the topic of licorice, as a fragrance. 

LibertyNatural.com’s product, Licorice “anise” Air Freshener.

I get it. A person finds themselves significantly hooked - fetishistically, even, in a sense, when it comes to some sort of purist decree, or something like that, on a licorice search, of all things. Sure, there’s star anise, fennel, and maybe one or two other things (in short), that smell “like” licorice, and on the other hand, this product ☝🏼 “is” fairly much licorice, and it says that it is licorice essential oil, for that matter. I suppose that star anise and fennel might be slightly distinct, but perhaps not. I’ll have to look in to that matter, at some point in the future. 

The company isn’t quite the quickest to ship things, but they are, as a basis, a farm, as a business, and I’d suppose that the people who work and manage the operation make a slim taking, on a sale, and that much of the time and attentions paid to things, of their business dailies, for example, end up being tending to the farm. But if you end up purchasing from them, please don’t give them a hassle about anything - they do ship their stuff they have listed, and it’s standardized and pure as any other decent supplier. They do also offer other licorice-like fragrance products, in their online offerings. Perhaps I’ll look in to experiencing those, as well, at some point, and I’ll report back on this topic. 

Just buy it from the site I told you to purchase it from, not some other place - you’re reading this, and I know how it is - having that feeling as though good enough isn’t good enough, when it comes to a licorice fragrance. This one is perfectly good and fine licorice fragrance, and perhaps there couldn’t be better, for that matter. 


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