Translate iPigeon.institute in to your native language 💱

Showing posts with label chemistry. Show all posts
Showing posts with label chemistry. Show all posts

Saturday, April 27

iPigeon.institute Local Botanical Item Spotlights - Mitica brand honeycomb, from Gelson's.

Update, and quick note: yipes! This product could potentially cause severe eye irritation! Be very wary about using the product described in this blog article, as far as cosmetic use goes. 


 One of my more recent fragrance fascinations was with the raw material, the honeycomb. I'd once had a great sample of Beeswax Absolute, which I highly enjoyed, and, which I'd mixed in to some fragrance compositions, with some slight attainment about them. I found the material very overpoweringly dominant, in what I felt, at the time, were small portions (I was just beginning to investigate and experiment with perfumery materials, having come from a background in making fragrance compositions with essential oils and absolutes that are more commonly found in local retail stores. 

In any case, I was fascinated by the physiological, or psychoactive (bioactive, perhaps, at least), effects of Beeswax Absolute, and, once I had run out of my sample product, I'd sometimes obsess over the ingredient, and I'd spend a lot of time, here and there, trying to find out new things to know about the product, itself, and I also developed a fascination with producing the absolute, myself, as well. 

Recently, I came across a great retail product beeswax honeycomb, by Mitica brand, which I found at Gelson's grocery store. I made sure to pick one up, since I had lots of money on my Food Stamps account, still. The item comes in its own frame and plastic box (which, for aroma chemical extraction, might not be the best material, but this is just my first try at producing my own agricultural fragrance ingredient from this material).

A top view of Mitica brand's honeycomb box, which includes a frame that the beeswax and honey, contained within the honeycomb, is built upon.

A diagonal view of Mitica's honeycomb box and frame. I felt that the product was ideal, over other choices in retail honeycomb availability, particularly on account of that a box and frame are included with the product.
I had not much knowledge base to work from, as far as discovering literature in regards to the chemical and molecular composition and form of honeycomb and beeswax material, so I had to do some looking up, of things. I had some notion that I could try to produce an alternative product to an absolute, using regular cooking vinegar. I tried it out, by soaking the honeycomb frame, in the box, and I felt that it could take weeks, or months, or more, perhaps, for a full extraction, as limited as with vinegar, solely, as the extraction fluid, although evaporation would be fairly reliable, I figured, and there could be useful compounds produced, with acetic acid thrown in to the equation, given that I be patient. 

At this point, it's been a few weeks, or so, and I noticed some slight changes - almost of that the beeswax seemed almost alive, in and of itself, even under vinegar, since I felt that some of the beeswax seemed to have creeped along, further out, on to the frame's top edges, where I don't remember seeing beeswax establishments, previously. The vinegar solution, itself, slowly became yellowish, but there wasn't a whole lot of action, in this instance of experimentation. 

Upon investigating the solvency considerations of the material, it was learned that the extraction would be best done with a polar solvent. I don't have any of the standard solvents, on hand, but, at one point, I became reminded that I have dimethyl octenone on hand, of which, I'd had previously employed a similar (somewhat) product, in doing an extraction and production method, as an experiment, with 3-octanone, as part of the extraction. Dimethyl octenone has a fairly relative olfactory scent profile to 3-octanone, and I figured that it is a polar solvent, in and of itself, perhaps as a scarce fraction of some other, more gross product of some other agricultural crop, in being separated, for qualitative purposes.

With a 15 mL bottle of dimethyl octenone, I was capable of pouring around a third, or less,  of the bottle out, in to the vinegar solution, and still cover the entire top surface area. Immediately, I noticed that the two layers didn't immediately mix; it was like oil and water, so I felt that my decision to employ dimethyl octenone was justified. This was yesterday. The liquid in the box became very vaporous, so I felt that perhaps a timeline of an extraction, in this experiment phase, would work along a much quicker timeline. If you'd notice, in the first photo, some of the honeycomb cells are destroyed, over on the top left. There are also some "breathing holes" that had developed, as a result of introducing the dimethyl octenone to the solvent solution (I shook the box, so the liquids became a more thorough solution). I figured, dimethyl octenone, pungent and musky solvent-smelling that it is, it'll eventually evaporate off; I should seek to establish more generalized visible similarities between what I produce, regardless of what it is, specifically, and if the viscosity, or consistency, in terms of the product's thickness, or solidity, becomes a familiar and standard sort of outcome, it would be easier to sit and wait for this type of portion of patience being necessary, being that dimethyl octenone might only dissipate over several weeks, or so, perhaps. 

Part of the challenge would be discovering what becomes of the wax, itself. I would typically take a "hands-off" approach to playing with my extraction experiments, and just stick to observation, and just the slightest of mixing, or disturbance of the solution, but, in this case, I touched the corner of the beeswax, and it melted like cake frosting, so I knew, then, that the extraction would be successful, from here. Only time will tell, as to what the outcome of this experiment will produce.

Update:

This honeycomb / beeswax project continues to reveal delicate mysteries about its form, within the acidic, polar solvent liquid At this stage, 4 days later, following the original post, the Mitica honeycomb's plastic box proves to have taken on acid damage, bearing leaks, and penetration, through the outer layers of plastic, whereas the now emulsified lipophilic liquid, which has incorporated the beeswax, as liquid beads, as an outer phase of emulsifier, wherein the solvent layer acts as the inner phase, with the dimethyl octenone / acetic acid, perhaps mixed with the plastic, somehow acting as a surfactant, to make the emulsification fairly molecularly small. Have a look! 



This (not so delicate) bulge is pretty resilient, in fact - almost like a rubbery latex, in texture, but definitely bendable and flexible, with the plastic walls having disintegrated, due to the particular nature of the acidic polar solvency of the solution. I'd suppose it would be a perfumer's hand at pulling off this trick; some of it is just gestural artistry, since I didn't know that this would happen - although if you did the same extraction, it very well could happen for you, also. 



Friday, March 3

How to: Easy homemade spice fragrance and flavor oleoresin collection with Wisesorb Flower Drying Silica Gel Crystals.

 I’ve come across a novel concept, in extending the use case scenario, in my studies and observations regarding chaparral plants of California, in the case of implementing Wisesorb’s Flower Drying Silica Gel Crystals - not only as a desiccant, yet I’ve found that it seems to bind spice | herb oleoresins to the structure of the silica particles.

Wisesorb Flower Drying Silica Gel Crystals, image courtesy of Amazon and Wisesorbent Technologies.

What does this mean, in particular?

Within the world of spices, I imagine that I would update this blog article, in days and weeks to come (I started on this project idea at the end of February, 2023) with exciting developments in detailing a rather simple and relatively labor and machinery-free method of processing fresh plant material in to an accessible pure oleoresin, which can be observed as in the image below:

A closeup of Wisesorb Silica Gel crystals with some fresh spice herb material and bits of oleoresin.

What an exciting thing to observe, for a fragrance and flavor enthusiast, perhaps with the added feature of bearing an artisanal crafting aspiration, in manufacturing ingredient concentrates from scratch. Imaginably, from this point, I could keep loading the silica gel crystals up with fresh spice herb materials until a satisfactory amount of oleoresin had built up in the crystals, at which point, I could perform a simple solvent extraction, of my choosing, of such, dependent, perhaps, upon the plant’s best reputed solvent, determined per species of harvested plant. In this instance, I came across a fresh, minty, mesquite-smelling chaparral plant in my local commonplace whereabouts.


Update: my backpack with this project, started, in it, had been stolen from me, so I can not currently continue this blog article. Hopefully, some day, I’ll be able to come back to it.


Monday, February 13

Product Review - Maison Margiela “Replica:” Jazz Club - Eau de Toilette.

This time, I tried out an unexpected “newcomer” fragrance. 

I hadn’t heard of Maison Margiela, prior to showing up at Nordstrom, out at the Del Amo Fashion Center, where I’d intended to show up to purchase Jo Malone’s Myrrh and Tonka - Cologne Intense (currently $160-$220 USD), as a departure from men’s fragrances I’d already tried, and loved, such as Dior Homme ($95-$175 USD - 1.7-6.7 oz.) or Viktor and Rolf Spicebomb ($134, 3.04 oz.). Prior to showing up, I’d tried to pore over exactly what I was trying to get at, here and there, in maintaining a fragranced personal profile, for people (not really) - the thought had come up, in my mind, as a suggestion, after all. Sure, Myrrh and Tonka smells great, but was it beyond something I could reasonably mix up, myself, somewhat, if I’d just purchased various component ingredients, myself? On one hand, Tonka bean is a bit of a contentious ingredient, being that it is potentially toxic. After the fact (of my purchase), I got some feedback on things. Supposedly, the toxins had been painstakingly researched and studied, as far as the end product fragrance composition, in question, and they’d duly been removed, from the consumer fragrance product - not all that far-fetched, to suppose. 

Then, at the men’s fragrance rack, at Nordstrom, the merchandising display winds up being a different story. I chose to do retail, at a department store, for one thing, for the sake of the fact that they have an on-site testing and auditioning space and capability, as far as product offerings, in fragrance - it’s something that e-commerce solutions, as far as branching out, in to something new, can - at times, be lacking in, resulting in purchases that lead to buyer’s remorse, perhaps, or a lack of diversification, which can wear down on things; concepts such as innovation. On the bottom of the fragrance rack, there were these products, named Replica, as a brand, which I had never heard of, before. I figured - “hmm… Replica? As though they might, somewhat, be fairly high-end aiming, (somewhat) bargain alternatives (at $150 USD, for 3.4 fl. oz.) to the more high-end and more well-established luxury lines, such as Jo Malone - in this case, I’d say that this brand is a bit of a newcomer, at Nordstrom, out here, whereas Creed products, far more expensive, which were placed at the top of the same section, on the same part of the fragrance rack, Jo Malone, right below, and some other brand, next one down, with Replica products seated at the bottom of the rack. My analytical mind had me supposing that perhaps these ones were a viable knock-off sort of thing, or otherwise cheaper alternative product, leading me astray from fulfilling my initial intention, in procuring a new fragrance for myself - so I don’t smell, while I’m out and about, in public, feeding the birds, and such. I do routinely become sweaty, and oh - what a travesty, if I end up smelling bad, as a known pigeon-feeding bum.

This is the product, similarly, as I’d encountered it, as a sample bottle, in-store, at Nordstrom. Maison Margiela’s Replica fragrance line touts itself as a rendition, if you would, upon a notable theme, or experience, per se. I found “Jazz Club” to be a suitable attention-grabbing alternative, given my initial intention to purchase Jo Malone’s Myrrh and Tonka cologne, for a fair sum of money more, on this instance of purchasing a bottle of cologne.

As it turns out, the general field of relevance, contextually - in a sensory sort of consideration, given the two top competitors, here - Myrrh and Tonka versus Jazz Club, I found my choice to wind up being reasonably within a similar olfactory ballpark, with Myrrh and Tonka’s lavender top notes becoming a citrusy and floral theme, with primofiore lemon and neroli, in Jazz Club. In addition, I’d also recently - by turn of fate, been interested in Rum, as a fragrance ingredient - quite expensive, as it turns out, and I feel that it’s a sophisticated ode to myrrh, on one hand, with its complexity and breadth, in a fragrance composition. The unifying features, between either one of them, were the sweet base notes of either one - Tonka bean versus vanilla bean: similar, in an olfactory sense, yet, upon sampling both fragrances in the store, I found Myrrh and Tonka to have a bit, perhaps, too much richness, in the bottom notes, and I felt that I would, at some point, measuring out a use-case scenario, of me being out and about, and sweating, and stuff - of that I’d develop a viciously rich musk about myself - easily offensive, if I ever got lazy, and I’d wind up “not realizing,” so to speak, how I smell, to other people, whereas I found Jazz Club’s features to accommodate the same general aesthetic, while remaining a bit bright, I’d say, as far as the overall effect, of the fragrance, whereas I could layer it with some still-there citrus and woodsy fragrances I have, in small amounts - Eau d’orange verte, by Hermes, and Dior Homme. Together, the trio of the three fragrances is deliciously elegant, like a luxuriantly-enveloped citrus rind, upon close examination, with the middle and base notes becoming more evident, with diffusion, starting at a slight distance, perhaps, with a slighter sniff of the nose. In my fragrance-wearing oeuvre and repertoire, of purchases-past, I’d enjoyed having what I’d say, would amount to a similar citrus-led layering of colognes, such as that the Hermes botanicals line of products would be most suitable - for instance: Eau de Citron Noir had been a recent favorite, with Dior Homme and Spicebomb as my layering choices - quite complex, in that instance. 

After purchasing, I tried on some of my choice, in purchasing, and I found it to have a delightful olfactory sense of that the fragrance imparted a notion of having taken a shower - ostensibly due to an addition of C-12 (I’d sensed - both Lauric Alcohol, as well as Aldehyde C-12; fairly bitter), with Alcohol C-12 (Lauric Alcohol) being the characteristic “just-showered” scent, of all scents, I’d say, and C-12 Aldehyde being a bit controversial for me, since I’m allergic to drinking alcohol, and overall, I found that this fragrance easily affects me with a notable depressive and sedated effect. It was my choice, though, in trying this one out, and perhaps it’s not all that much, to my detriment, overall. I’m trying to do life as representatively (as much as possible) not overly, or obviously, stimulated - it’s simply too cheaply and easily a topic of controversy, and I strive to be an honest role model of sustainability in my enterprise model, so I don’t get thrown out of town - quite literally, that, which could wind up, being the case, for me. I figure - if I take the bottle out, with me, on a walk, and with my ionic mineral carry-along profile, and with my travels equating to some form of milling, further, of the product, the fragrance would, ostensibly, mill out the aldehyde, or I could throw some other stuff in there, since the bottle actually allows for the entire spray top, and “cap” of the bottle, to be removed - allowing for additions, or refills, for example, another ingredient, or entire fragrance, could be put in to this bottle of Jazz Club, thus transforming the presence of this contentious (for me, being allergic to “drinking” alcohol) Aldehyde C-12 ingredient in to something altogether unexpected, and far-removed, sensory-wise, in the fragrance composition, in my experience with aldehyde C-12.

A nice touch, that the bottle’s top is removable, allowing for refills. 

I’ll leave this review, at that, for the time being. Thanks for reading :)

Latest post.

Local DTLA Pigeon Genetic Milestones - Academic Evidence

  As it's been around 7 years that I'd been visiting the local Downtown Los Angeles pigeon flocks and keeping this blog, several bre...

iPigeon.institute’s most popular recent blog articles and posts